## Abstract Thermolysis of the “all‐__cis__” compound 1α‐chloro‐2α,3α‐dimethylcyclopropane (A) at 550–607 K and 6–115 torr is a first‐order homogeneous non‐radical‐chain process giving penta‐1,3‐diene (PD) and HCl as products. The Arrhenius parameters are log~10~__A__(sec^−1^) = 13.92 ± 0.08 and __
Radical Opening Reaction of Glucosyl 1,2-Cyclopropane Derivatives: Synthesis of α and β C-Glycosides and Oxepane Derivatives.
✍ Scribed by Paramita Kar; K. Nagaiah; M. K. Gurjar
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 36 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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Stereoselective Synthesis of α-C-(Alkynyl)-glycosides via Ring-Opening of α-1,2-Anhydrosugars. -In the presence of ZnCl2 the α-1,2-epoxide function in sugars is selectively ring-opened by lithium alkynyl derivatives to form α -glycosides with retention of configuration. -
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