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Hydrolysis of tetrakis-μ-acetylsalicylato-dicopper(II)

✍ Scribed by A. A. Alich; L. E. Wittmers


Book ID
102407385
Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
382 KB
Volume
69
Category
Article
ISSN
0022-3549

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Colourless crystals of the title compound, [Cu 2 (C 4 N 3 ) 2 -(C 18 H 15 P) 4 ], were obtained by the reaction of CuC(CN) 3 with excess of molten PPh 3 . The crystal structure contains centrosymmetric dimeric units bridged by two C(CN) 3 ligands. The Cu atoms have a distorted tetrahedral coordinati