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Tetrakis(μ-acetato)bis(2-pyridone)dicopper

✍ Scribed by Blake, A. J. ;Gould, R. O. ;Winpenny, R. E. P.


Book ID
114508052
Publisher
International Union of Crystallography
Year
1991
Tongue
English
Weight
345 KB
Volume
47
Category
Article
ISSN
0108-2701

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✍ Bessler, Karl E. ;Calzavara, Leandro A. de P. ;Deflon, Victor M. ;Niquet, Elke 📂 Article 📅 2001 🏛 International Union of Crystallography 🌐 English ⚖ 203 KB

Colourless crystals of the title compound, [Cu 2 (C 4 N 3 ) 2 -(C 18 H 15 P) 4 ], were obtained by the reaction of CuC(CN) 3 with excess of molten PPh 3 . The crystal structure contains centrosymmetric dimeric units bridged by two C(CN) 3 ligands. The Cu atoms have a distorted tetrahedral coordinati