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Bis(μ-tri­cyano­methanido)­tetrakis­(tri­phenyl­phosphine)­dicopper(I)

✍ Scribed by Bessler, Karl E. ;Calzavara, Leandro A. de P. ;Deflon, Victor M. ;Niquet, Elke

Book ID
104478884
Publisher
International Union of Crystallography
Year
2001
Tongue
English
Weight
203 KB
Volume
57
Category
Article
ISSN
1600-5368

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✦ Synopsis

Colourless crystals of the title compound, [Cu 2 (C 4 N 3 ) 2 -(C 18 H 15 P) 4 ], were obtained by the reaction of CuC(CN) 3 with excess of molten PPh 3 . The crystal structure contains centrosymmetric dimeric units bridged by two C(CN) 3 ligands. The Cu atoms have a distorted tetrahedral coordination.

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