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Hydrogenation of cyclohexene and benzene on Re2(CO)10

โœ Scribed by M. A. Ryashentseva; Kh. M. Minachev; V. N. Khandozhko; P. E. Kolobova


Book ID
112494422
Publisher
Springer
Year
1990
Tongue
English
Weight
210 KB
Volume
39
Category
Article
ISSN
1573-9171

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Facile heterogeneous catalytic hydrogena
โœ Norman L. Holy ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 188 KB

The DMF-soluble rhodium (I) complex of N-phenylanthranilic acid (1) is a remarkably active hydrogenation catalyst. It readily converts benzene to cyclohexane at room temperature and 1 atm of hydrogen.' The only other homogeneous catalyst displaying similar activity is 3 n -C3H5Co[P(OCH3)313, but thi