Cyclohexene decomposition on Ru(001) and the mechanism of benzene hydrogenation
β Scribed by D.K. Flynn; J.A. Polta; P.A. Thiel
- Publisher
- Elsevier Science
- Year
- 1987
- Weight
- 410 KB
- Volume
- 185
- Category
- Article
- ISSN
- 0167-2584
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## Potassium hydrosidc is formed when vatcr is adsorbed at 80 K on 3 Ru(O0 1) surface precovered wirh potassium. The vibrational spectrum of KOH obtained whh EELS is characterized by an OH stretch at 3570-3670 cm-'; 1~ svx a~ 1340-l 500 cm-' and 200-800 cm-' are tentatively assigned to KOH bending
## Abstract The rate of hydrogenation of cyclohexene, catalyzed by CoH~3~(PPh~3~)~3~, has been measured under various conditions and, based on these data, a mechanism has been postulated. For the individual steps of the mechanism enthalpy and entropy differences have been determined. The interpreta