✦ LIBER ✦

Facile heterogeneous catalytic hydrogenation of benzene and cyclohexene

✍ Scribed by Norman L. Holy

Book ID: 104235628
Publisher: Elsevier Science
Year: 1977
Tongue: French
Weight: 188 KB
Volume: 18
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)83331-1

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✦ Synopsis

The DMF-soluble rhodium (I) complex of N-phenylanthranilic acid (1) is a remarkably active hydrogenation catalyst. It readily converts benzene to cyclohexane at room temperature and 1 atm of hydrogen.' The only other homogeneous catalyst displaying similar activity is 3 n -C3H5Co[P(OCH3)313, but this catalyst is considerably more difficult to prepare and has an ':

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