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Hydrogenation of Alkenes Catalyzed by Dinuclear Thiolato Bridged Rhodium(I) Complexes

✍ Scribed by Philippe Kalck; Rene Poilblanc; Rene-Paul Martin; Alain Rovera; Antoine Gaset

Book ID
108354272
Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
252 KB
Volume
195
Category
Article
ISSN
0022-328X

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Rhodium-Catalyzed Hydrogenation of Alken
Rhodium-Catalyzed Hydrogenation of Alkenes by Rhodium/Tris(fluoroalkoxy)phosphane Complexes in Fluorous Biphasic System
✍ Denis Sinou; David Maillard; Ali Aghmiz; Annaβ€…M. Masdeuβ€…i-BultΓ³ πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 143 KB πŸ‘ 1 views

The reaction of [Ir(m-Cl)(COD)] 2 with various fluorous derivatives of triphenylphosphane containing a para-, meta-, or ortho-(1H,1H-perfluoroalkoxy)-substituted fluorous phosphane P(C 6 H 4 -ORf) 3 (Rf CH 2 C 7 F 15 , CH 2 CH 2 CH 2 C 8 F 17 ) and CO (1 atm) gives the corresponding trans-[Ir(m-Cl)(