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Correlation of rates of alkene hydrogenation catalyzed by rhodium complexes

โœ Scribed by M. Kraus


Book ID
103692670
Publisher
Elsevier Science
Year
1987
Weight
259 KB
Volume
43
Category
Article
ISSN
0304-5102

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Rhodium-Catalyzed Hydrogenation of Alken
โœ Denis Sinou; David Maillard; Ali Aghmiz; Annaโ€…M. Masdeuโ€…i-Bultรณ ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 143 KB ๐Ÿ‘ 1 views

The reaction of [Ir(m-Cl)(COD)] 2 with various fluorous derivatives of triphenylphosphane containing a para-, meta-, or ortho-(1H,1H-perfluoroalkoxy)-substituted fluorous phosphane P(C 6 H 4 -ORf) 3 (Rf CH 2 C 7 F 15 , CH 2 CH 2 CH 2 C 8 F 17 ) and CO (1 atm) gives the corresponding trans-[Ir(m-Cl)(