Hydrogenation of 4-(3,5-dimethyl-4-isoxazoylmethyl)-7,7a-dihydro-1.beta.-hydroxy-7a.beta.-methyl-5(6H)-indanone
β Scribed by McKenzie, Thomas C.
- Book ID
- 120366992
- Publisher
- American Chemical Society
- Year
- 1974
- Tongue
- English
- Weight
- 385 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
The title compound, C 12 H 14 N 6 , was synthesized via cyclocondensation of 5-guanidino-3-phenyl-1,2,4-triazole with acetone. Only one tautomeric form with the NH H atom vicinal to the methyl groups was observed in the crystal structure. The triazine ring adopts a flattened half-boat conformation.
The title compound, C 11 H 15 N 3 O 6 S, is a 2 0 ,3 0 -thiazine-fused bicyclic nucleoside. The furanose ring adopts a 3 0 -endo,4 0 -exo conformation 4 T 3 . The orientation of the pyrimidine ring is anti with respect to the sugar group. The crystal packing is stabilized by intermolecular N-HΓ Γ ΓO
Hexahydro-4a-methyl-7,7-diphenyl-1(2H)-naphthalenone. -A clean and efficient route to the hitherto not reported title compound (VIII) starting from the known 3-ethenylcyclohexanone (I) is given. The approach represents a general strategy for the synthesis of related 7,7-diarylhexahydronaphthalenone