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Hydrogen-Transfer Catalysis with Pincer-Aryl Ruthenium(II) Complexes

✍ Scribed by Paulo Dani; Thomas Karlen; Robert A. Gossage; Serafino Gladiali; Gerard van Koten

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
81 KB
Volume
39
Category
Article
ISSN
0044-8249

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Hydrogen-Transfer Catalysis with Pincer-
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Complexes of pincerlike aryl ligands such as 1 Β± 3 belong to a new class of homogeneous catalytic systems that contain a stable metal Β± carbon s bond. [1, 2a] Such organometallic complexes have already been used in a number of metal-mediated organic transformations, for example, dehydrogenation, [2a

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## Abstract Achiral P‐donor pincer‐aryl ruthenium complexes ([RuCl(PCP)(PPh~3~)]) 4c,d were synthesized __via__ transcyclometalation reactions by mixing equivalent amounts of [1,3‐phenylenebis(methylene)]bis[diisopropylphosphine] (2c) or [1,3‐phenylenebis(methylene)]bis[diphenylphosphine] (2d) and