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ChemInform Abstract: Hydrogen-Transfer Catalysis with Pincer-Aryl Ruthenium(II) Complexes.

✍ Scribed by Paulo Dani; Thomas Karlen; Robert A. Gossage; Serafino Gladiali; Gerard van Koten

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
31
Category
Article
ISSN
0931-7597

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## Abstract Achiral P‐donor pincer‐aryl ruthenium complexes ([RuCl(PCP)(PPh~3~)]) 4c,d were synthesized __via__ transcyclometalation reactions by mixing equivalent amounts of [1,3‐phenylenebis(methylene)]bis[diisopropylphosphine] (2c) or [1,3‐phenylenebis(methylene)]bis[diphenylphosphine] (2d) and