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Hydrogen peroxide mediated efficient amidation and esterification of aldehydes: Scope and selectivity

✍ Scribed by Tank, Rekha; Pathak, Uma; Vimal, Manorama; Bhattacharyya, Shubhankar; Pandey, Lokesh Kumar


Book ID
120358950
Publisher
Royal Society of Chemistry
Year
2011
Tongue
English
Weight
202 KB
Volume
13
Category
Article
ISSN
1463-9262

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Aldehydes were efficiently converted directly into the corresponding gem-dihydroperoxides (DHPs) on treatment with aqueous 70% H 2 O 2 in a biphasic system with ether catalyzed by camphorsulfonic acid. The synthesis represents the most versatile access to this class of compounds.