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A simple, efficient and versatile synthesis of primary gem-dihydroperoxides from aldehydes and hydrogen peroxide

✍ Scribed by Alexander Bunge; Hans-Jürgen Hamann; Jürgen Liebscher

Book ID
104096039
Publisher
Elsevier Science
Year
2009
Tongue
French
Weight
187 KB
Volume
50
Category
Article
ISSN
0040-4039

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✦ Synopsis

Aldehydes were efficiently converted directly into the corresponding gem-dihydroperoxides (DHPs) on treatment with aqueous 70% H 2 O 2 in a biphasic system with ether catalyzed by camphorsulfonic acid. The synthesis represents the most versatile access to this class of compounds.

📜 SIMILAR VOLUMES

Studies on Novel Synthetic Methodologies
Studies on Novel Synthetic Methodologies. Part 149. A Simple and Efficient Synthesis of gem-Dihydroperoxides from Ketones Using Aqueous Hydrogen Peroxide and Catalytic Ceric Ammonium Nitrate.
✍ Biswanath Das; Maddeboina Krishnaiah; Boyapati Veeranjaneyulu; Bommena Ravikanth 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 25 KB 👁 1 views

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