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Hydrogen peroxide decomposition on manganese oxide (pyrolusite): Kinetics, intermediates, and mechanism

✍ Scribed by Si-Hyun Do; Bill Batchelor; Hong-Kyun Lee; Sung-Ho Kong


Book ID
116361005
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
287 KB
Volume
75
Category
Article
ISSN
0045-6535

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Oscillatory change of pH occurs during the chromate-catalyzed decomposition of hydrogen peroxide in a weakly acidic medium at elevated temperature and at high initial concentration of hydrogen peroxide. In a closed system, there are only two or three periods, but sustained oscillation occurs in a CS