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Kinetics and mechanism of oxidation of manganese(III) acidoporphyrin complexes with hydrogen peroxide

✍ Scribed by T. N. Lomova; E. N. Kiseleva; M. E. Klyueva

Book ID
110180462
Publisher
SP MAIK Nauka/Interperiodica
Year
2006
Tongue
English
Weight
227 KB
Volume
51
Category
Article
ISSN
0036-0236

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Oxidation of (+)-3-carene (1), nerol (2) and geraniol (3) by hydrogen peroxide in the presence of catalytic amounts of several manganese(III) porphyrin complexes with electron withdrawing and electron donating groups was examined. The reactions were carried out at room temperature in acetonitrile, u