Catalytic Decomposition of Hydrogen Peroxide on Iron Oxide: Kinetics, Mechanism, and Implications
β Scribed by Lin, Shu-Sung; Gurol, Mirat D.
- Book ID
- 111972367
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 159 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0013-936X
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The hydrogen peroxide decomposition kinetics were investigated for both "free" iron catalyst [Fe(II) and Fe(III)] and complexed iron catalyst [Fe(II) and Fe(III)] complexed with DTPA, EDTA, EGTA, and NTA as ligands (L). A kinetic model for free iron catalyst was derived assuming the formation of a r
The decomposition of alkaline hydrogen peroxide solutions at 20Β°C has been studied in the presence of both supported iron catalysts and in systems with iron initially in solution. Studies with an iron-alumina supported catalyst showed the decomposition reaction was first order with respect to total