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Hydrogen Bonding in α-Aminophosphonic Acids

✍ Scribed by Bogomilova, Anita; Hägele, Gerhard; Troev, Kolio; Wagner, Ernst; Günther, Michael


Book ID
118746058
Publisher
Taylor and Francis Group
Year
2012
Tongue
English
Weight
706 KB
Volume
187
Category
Article
ISSN
1042-6507

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Enantioselective synthesis of α-aminopho
✍ Ute Schmidt; Hans Walter Krause; Günther Oehme; Manfred Michalik; Christine Fisc 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 208 KB 👁 1 views

Chiral ␣-aminophosphonic acid derivatives are efficiently synthesized by asymmetric hydrogenation of the prochiral N-acyl-␣,␤-dehydroaminophosphonates. PROPRAPHOS-Rh-catalysts from readily available (S)-and (R)-Propranolol proved to be suitable in the homogenous reaction affording an enantiomeric ex