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Hydrogen Bond, Tautomerism, and Structure of 2-Nitroresorcinol: A Microwave Spectroscopy Study

โœ Scribed by W. Caminati; B. Velino; R. Danieli

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
415 KB
Volume
161
Category
Article
ISSN
0022-2852

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โœฆ Synopsis

The microwave spectra of 2-nitroresorcinol and of its (\mathrm{O}-\mathrm{D}) mono- and dideuterated species have been investigated in the frequency range (28-40 \mathrm{GHz}). The assigned spectra belong to a planar tautomer with (C_{2 v}) symmetry and two internal hydrogen bonds between the two hydroxyl groups and the two nitro group oxygens. The rotational spectra of four vibrational satellites of two low energy vibrations have also been assigned for the normal isotopomer. @ 1993 Academic Press, Inc.

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