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Characterization by Microwave Spectroscopy of a Transient Hydrogen-Bonded Complex of Oxirane and Hydrogen Chloride Isolated in a Pulsed Jet

✍ Scribed by Prof. Anthony C. Legon; Dr. Christopher A. Rego


Publisher
John Wiley and Sons
Year
1990
Tongue
English
Weight
278 KB
Volume
29
Category
Article
ISSN
0044-8249

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Dipole moment enhancement on formation o
✍ A.C. Legon; D.J. Millen; S.C. Rogers πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 241 KB

The microwave spectrum of the heterodimer EKYbMF is reported, the collinearity of the nuclei establislIed, and ro(N--F) = 2.796 A obtained. From the Stark effect, ~10 (tiCN4iF) = 5.59 r 0.02 D which indicates an enhancement of 0.78 D over the vector sum of the monomer values.