Hydrodynamic theory for vibrational relaxation in liquids
โ Scribed by Metiu, Horia; Oxtoby, David W.; Freed, Karl F.
- Book ID
- 117997984
- Publisher
- The American Physical Society
- Year
- 1977
- Tongue
- English
- Weight
- 683 KB
- Volume
- 15
- Category
- Article
- ISSN
- 1050-2947
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
We discuss the relationship between vibrational population relaxation, loss of phase coharence, and the homogeneously broadened spontaneous poklzed Raman linewidth. We derive a general equation reltmg these quantitres. and show that extension of the simple model (where the coupling to the heat bath
Published experiment& data on the Raman fine widths of some al bands of methyl iodide and benzene are compared with theoretical predktions of relaxation theories which assume either rapid or slow time scales for intermofecular ffuctuations. The observed variations with density and with mole fraction