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Hydrocarbon σ-radical cations

✍ Scribed by Tatyana E. Shubina; Andrey A. Fokin


Book ID
112232670
Publisher
Wiley (John Wiley & Sons)
Year
2011
Tongue
English
Weight
825 KB
Volume
1
Category
Article
ISSN
1759-0876

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Deprotonation of hydrocarbon radical cat
✍ D.W. Werst; E.A. Piocos; E.E. Tartakovsky; A.D. Trifunac 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 697 KB

Neutral radicals are observed at 77 K following radiolysis of cycloheptatriene and cyclohexane adsorbed on ZSM-5 zeolites. The mechanism of radical formation is assigned to proton transfer from the sorbate radical cations to the zeolite lattice. In the case of cycloheptatriene, the ratio C,H;/C,H,+'