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Reversible σ-Dimerizations of Persistent Organic Radical Cations

✍ Scribed by Chen, Xiaoyu; Wang, Xingyong; Zhou, Zhaoyi; Li, Yizhi; Sui, Yunxia; Ma, Jing; Wang, Xinping; Power, Philip P.


Book ID
118752358
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
520 KB
Volume
52
Category
Article
ISSN
0044-8249

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Attempts to generate the radical cations of nitroalkanes using the standard procedure of exposing dilute solutions in fluorotrichloranethane at 77 K to ionizing radiation gave 1~ yields of the expected prcducts, having a SOMO confined. to oxygen as judged by their e.s.r. spectra, together with a sp