Hydrocarbon Cation Radical Formation by Reduction of Peroxydisulfate
β Scribed by Fabrizio, Eve F.; Prieto, Inmaculada; Bard, Allen J.
- Book ID
- 127244467
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 46 KB
- Volume
- 122
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Absinz& The selected diaikyi dithioethers l,S-dithiocane, 1,4-dithiepane, 1,4-dithione, and 2,6\_dithiaheptone are readily monoaIkyIoted in nitromethane by tert-butyl tMij7uoromethanesulfonyI-3-hydro~perogproponoate, 4 to give the corresponding suifonium salt peresters 2a-c, and 3 in good yieId. Los
Neutral radicals are observed at 77 K following radiolysis of cycloheptatriene and cyclohexane adsorbed on ZSM-5 zeolites. The mechanism of radical formation is assigned to proton transfer from the sorbate radical cations to the zeolite lattice. In the case of cycloheptatriene, the ratio C,H;/C,H,+'