The oxidation of 3,6-dehydrohomoadamantane (1) was the activation processes. Isomeric radical cations formed from different precursors can equilibrate with low barriers achieved under chemical (NO + BF 4 -/EtOAc, NO + OAc -/Ac 2 O, and NO + BF 4 -/CH 3 CN), photochemical (photoexcited 1,2,4,5-(2.0-1
A Stable Radical-Cation of a Hydrocarbon
✍ Scribed by Prof. Dr. S. Hünig; Dipl.-Chem. D. Scheutzow; Dr. H. J. Friedrich
- Publisher
- John Wiley and Sons
- Year
- 1964
- Tongue
- English
- Weight
- 124 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0044-8249
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## Abstract For Abstract see ChemInform Abstract in Full Text.
Neutral radicals are observed at 77 K following radiolysis of cycloheptatriene and cyclohexane adsorbed on ZSM-5 zeolites. The mechanism of radical formation is assigned to proton transfer from the sorbate radical cations to the zeolite lattice. In the case of cycloheptatriene, the ratio C,H;/C,H,+'
The distonic radical cation HC+ (OH)ObH,, an isomer of ionized methyl formate HC(O)OCH$', has been generated from fragmentation of ionized isobutyl formate and ionized 2-methylbutyl formate and characterized by collisional activation (CA) and neutralization-reionization (NR) mass spectrometries. A m