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Hydroboration of vinylglycine and allylglycine as a route to boron-derivatives of α-amino acids

✍ Scribed by Valérie Denniel; Patrick Bauchat; Daniel Danion; Renée Danion-Bougot

Book ID
103410591
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
227 KB
Volume
37
Category
Article
ISSN
0040-4039

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Enantioselective decarboxylation–reproto
Enantioselective decarboxylation–reprotonation of an α-amino malonate derivative as a route to optically enriched cyclic α-amino acid
✍ Louis M.-A. Rogers; Jacques Rouden; Ludovic Lecomte; Marie-Claire Lasne 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 119 KB

Chiral tertiary amines have been examined as enantioselective decarboxylation-reprotonation reagents for the synthesis of a-amino acids via a-aminomalonates. N-Acetyl pipecolic acid ethyl ester, as a model compound, was obtained in good yield and 52% enantiomeric excess using a quinidine derived bas