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Hydride shift in the solvolysis of 5-substituted PGi1 derivatives

✍ Scribed by I. Tömösközi; G. Galambos; K. Kánai; P. Gyõry; L. Gruber; J. Tamás; Gy. Bujtás

Book ID
107857214
Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
542 KB
Volume
38
Category
Article
ISSN
0040-4020

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✍ Klaus-Peter Jäckel; Michael Hanack 📂 Article 📅 1975 🏛 Elsevier Science 🌐 French ⚖ 137 KB

Recently we reprted about the first example of a 1.2-hydride shift durmg the generation of a vrnyl cation, a process well known for trlsubstituted car&mum ions 2) :Thls was obsermildurlng the solvolys~s of cls-and trans-3-cyclop~l-2-propen-2-yl-trifl~~~esulfo~~(tnflate)3! --The 1.2-hydride shLft was