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1,5-Hydride Shift in the Aluminum Chloride Promoted Allylsilylation of 5-Silyl-1-alkenes

✍ Scribed by Choi, Geun Mook; Yoo, Bok Ryul; Lee, Ho-Jin; Lee, Kang-Bong; Jung, Il Nam


Book ID
127072069
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
135 KB
Volume
17
Category
Article
ISSN
0276-7333

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[1,2]-hydride shifts in the reaction of
✍ Masajiro Kawana; Sakae Emoto πŸ“‚ Article πŸ“… 1975 πŸ› Elsevier Science 🌐 French βš– 221 KB

Despite the extensive amount of research on nonenzymatic [1,2]-hydride shifts.2 there have been particularly few reports on similar transfers related to carbohydrates.3 We wish to report here the novel example of the stereoselective [1,2]-hydride shifts which occured in the reactions of methyl 3-0-m