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Hydride Affinity Scale of Various Substituted Arylcarbeniums in Acetonitrile

โœ Scribed by Zhu, Xiao-Qing; Wang, Chun-Hua

Book ID
120300800
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
1017 KB
Volume
114
Category
Article
ISSN
1089-5639

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Hydride affinities of carbenium ions in
Hydride affinities of carbenium ions in acetonitrile and dimethyl sulfoxide solution
โœ Cheng, Jinpei; Handoo, Kishan L.; Parker, Vernon D. ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 739 KB

Hydride affinities of organic cations in solution, defined as the free energy change for the reaction (R+)s + (H-)s a (RH),, where the subscript s refers to the solvent, can be determined using either of two equations (eqs 5 and 7) derived from thermochemical cycles. The degree of uncertainty in AGh