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Hydride Affinities of Arylcarbenium Ions and Iminium Ions in Dimethyl Sulfoxide and Acetonitrile

โœ Scribed by Zhang, Xian-Man; Bruno, Joseph W.; Enyinnaya, Emmeline

Book ID
121403835
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
107 KB
Volume
63
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES

Hydride affinities of carbenium ions in
Hydride affinities of carbenium ions in acetonitrile and dimethyl sulfoxide solution
โœ Cheng, Jinpei; Handoo, Kishan L.; Parker, Vernon D. ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 739 KB

Hydride affinities of organic cations in solution, defined as the free energy change for the reaction (R+)s + (H-)s a (RH),, where the subscript s refers to the solvent, can be determined using either of two equations (eqs 5 and 7) derived from thermochemical cycles. The degree of uncertainty in AGh