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Determination of Hydride Affinities of Various Aldehydes and Ketones in Acetonitrile

โœ Scribed by Zhu, Xiao-Qing; Chen, Xi; Mei, Lian-Rui

Book ID
126841657
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
712 KB
Volume
13
Category
Article
ISSN
1523-7060

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Hydride affinities of carbenium ions in
Hydride affinities of carbenium ions in acetonitrile and dimethyl sulfoxide solution
โœ Cheng, Jinpei; Handoo, Kishan L.; Parker, Vernon D. ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› American Chemical Society ๐ŸŒ English โš– 739 KB

Hydride affinities of organic cations in solution, defined as the free energy change for the reaction (R+)s + (H-)s a (RH),, where the subscript s refers to the solvent, can be determined using either of two equations (eqs 5 and 7) derived from thermochemical cycles. The degree of uncertainty in AGh