Hydride abstraction in fast atom bombardment
β Scribed by Michael A. Baldwin; Kevin J. Welham; Istvan Toth; William A. Gibbons
- Publisher
- John Wiley and Sons
- Year
- 1988
- Tongue
- English
- Weight
- 332 KB
- Volume
- 23
- Category
- Article
- ISSN
- 1076-5174
No coin nor oath required. For personal study only.
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The effects on fast atom bombardment (FAB) mass spectra of analyte bases in glycerol on adding acids were investigated. The MH+ ion intensity usually increased but sometimes decreases were also found. For the practical use of FAB, it is important to clarify the reasons for this acid effect. By criti
## Abstract Examples of various chemical reactions occurring in the matrix or in the selvedge region in fast atom bombardment (FAB) mass spectrometry are discussed. These are categorized as oxidations and reductions; substitutions; clusterings and additions; and sample decomposition or transformati