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Chemical reactions in fast atom bombardment mass spectrometry

✍ Scribed by Károly Vékey; Luigi F. Zerilli

Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
492 KB
Volume
26
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

Examples of various chemical reactions occurring in the matrix or in the selvedge region in fast atom bombardment (FAB) mass spectrometry are discussed. These are categorized as oxidations and reductions; substitutions; clusterings and additions; and sample decomposition or transformation. Some reactions observed showed significant time behaviour and in one case it was possible to determine rate constants. These data suggest that chemical reactions can be accelerated significantly by fast atom bombardment.

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