Hydration-dehydration of the electroactive group on the electrochemical behaviour of pyridoxal-5′-phosphate
✍ Scribed by M. Blazquez; R. Izquierdo; F. Garcia-Blanco; M. Dominguez
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 386 KB
- Volume
- 16
- Category
- Article
- ISSN
- 1567-5394
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We determined the apparent equilibrium constant of formation, KpH, of the Schijf bases of pyridoxal 5'-phosphate (PLP) and poly-and copolymers containing L-lysine, as a function of pH at 25" and a constant ionic strength of 0 . 1 ~. The KPH values obtained at acidic and neutral pH were larger that t
## Abstract The stability of some Schiff‐bases formed between PLP and different amino acids has been investigated in a wide range of pH. The kinetic constants of formation of these compounds and their hydrolysis rate constants have been determined. Results show that the α‐position of the carboxyl g