Homolytic Bond Dissociation Enthalpies of C–C and C–H Bonds in Highly Crowded Alkanes
✍ Scribed by Chen ZHU; Lei RUI; Yao FU
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 138 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0256-7660
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## Abstract For Abstract see ChemInform Abstract in Full Text.
Acidities and bond dissociation energies (BDEs) of the N-H bond in two phenylsulfenylamides, PhSNHBz and PhSNH-t-Bu, and four phenylsulfenylanilides, 4-GC 6 H 4 NHSPh, where G = MeO, H, Br and CN, were measured in order to compare the effects of substituents on acidities and BDEs of N-H bonds with t
The acidities of the two different sites in naphthalene (1alpha and 1beta) and the electron affinities of the alpha- and beta-naphthyl radicals were measured using a Fourier transform mass spectrometer. Both carbon-hydrogen bond dissociation energies for naphthalene also were obtained, in this case