Sublimation study of triphenyl boron and the bond-dissociation enthalpy of BC6H5
✍ Scribed by Steven W. Govorchin; Adli S. Kana'an; Joseph M. Kanamueller
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 434 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0021-9614
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The standard molar enthalpy of sublimation of Fe(c-C5H5)2,bis(h-cyclopentadienyl)iron(II), ferrocene, has been experimentally determined by the Knudsen-effusion method using a quartz-crystal microbalance. The results from two series of experiments were found to be DsubH°m(298.15 K)=(74.3420.41) kJ•m
The successive C-H bond dissociation energies of CH,, &Hz. C2H4, and H&O (ketene) are determined using large basis sets and a high level of correlation treatment. For CHI, C2H2, and C2H4 the computed values are in excellent agreement with experiment. Using our results we recommend 107.9 +2.0 and 96.