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Homolytic amidation of heteroaromatic bases: a new selective process

โœ Scribed by G.P. Gardini; F. Minisci; G. Palla; A. Arnone; R. Galli

Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
188 KB
Volume
12
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES

A new selective type of aromatic substit
A new selective type of aromatic substitution: homolytic amidation
โœ F. Minisci; G.P. Gardini; R. Galli; F. Bertini ๐Ÿ“‚ Article ๐Ÿ“… 1970 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 119 KB

The prevalent nucleophilic character of the alkyl radicals' readily permits thehomolyticalkylation of protonated heteroaromatic bases2, due to the contribution of polar forms in the transition state: The oxygen atom of ethersand alcohols as well as the nitrogen of amides and amines, attached to the