Homolytic aromatic substitution: A simple route to the aldehydes of heteroaromatic bases

A new route to 2,4-dibenzyltetrahydroqui

A new route to 2,4-dibenzyltetrahydroquinoline. Reversibility of the homolytic aromatic benzylation.

✍ O. Porta; G. Sesana 📂 Article 📅 1978 🏛 Elsevier Science 🌐 French ⚖ 195 KB

The benzyl radical addition to ethylene is a reversible process at 9OOC'. Considering that the addition of a free radical to benzene has been estimated2 to be less exothermic of ca. 11 Kcal/mole than the corresponding addition of a benzyl radical to ethylene, the addition of a benzyl radical to an a

The iodotrichlorosilane induced reaction

The iodotrichlorosilane induced reactions of aromatic aldehydes with acrylonitrile : a unique route to unsaturated iminoaldehydes

✍ Saad S. Elmorsy; Duria S. Badawy; Mohamed A. Nour; Andrew Pelter 📂 Article 📅 1991 🏛 Elsevier Science 🌐 French ⚖ 114 KB

We describe a unique interaction of aromatic aldehydes with acrylonitrile, induced by iodotrichlorosilane (ITCS), which directly yields arylidene-3-aminoprop-2-enals. We recently disclosed' a unique and general redox reaction of aliphatic or aromatic aldehydes with simple aliphatic or aromatic nitr

ChemInform Abstract: Catalytic, Highly E

ChemInform Abstract: Catalytic, Highly Enantioselective Friedel—Crafts Reactions of Aromatic and Heteroaromatic Compounds to Trifluoropyruvate. A Simple Approach for the Formation of Optically Active Aromatic and Heteroaromatic Hydroxy Trifluoromethyl Esters.

✍ Wei Zhuang; Nicholas Gathergood; Rita G. Hazell; Karl Anker Joergensen 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 32 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

ChemInform Abstract: A Simple Method for

ChemInform Abstract: A Simple Method for the Synthesis of Substituted Benzylic Ketones: Homologation of Aldehydes via the in situ Generation of Aryldiazomethanes from Aromatic Aldehydes.

✍ Steven R. Angle; Martin L. Neitzel 📂 Article 📅 2001 🏛 John Wiley and Sons ⚖ 33 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

The lithiation and alkylation of 4-(2′-a

The lithiation and alkylation of 4-(2′-alkenesulphinyl)-morpholines, a simple route to substituted allylic sulphinamides

✍ Jean-Bernard Baudin; Sylvestre A. Julia 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 210 KB

ChemInform Abstract: Propylphosphonic An

ChemInform Abstract: Propylphosphonic Anhydride (T3P®): A Remarkably Efficient Reagent for the One-Pot Transformation of Aromatic, Heteroaromatic, and Aliphatic Aldehydes to Nitriles.

✍ John Kallikat Augustine; Rajendra Nath Atta; Balakrishna Kolathur Ramappa; Chand 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB 👁 1 views