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Homogeneous hydroformylation of olefins by cis-[PtCl2(PPh3)2]/SnCl2

✍ Scribed by Guillermio Muller; Daniel Sainz; Joaquim Sales

Publisher
Elsevier Science
Year
1990
Weight
455 KB
Volume
63
Category
Article
ISSN
0304-5102

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Asymmetric hydroformylation of styrene w
Asymmetric hydroformylation of styrene with PtCl2(atropoisomeric diphosphine)SnCl2 systems
✍ Alberto Scrivanti; Stefano Zeggio; Valentina Beghetto; Ugo Matteoli πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 353 KB

The new chiral complex [ PtQ{ (S) -( -) -MeOBIPHEP) 1, where MeOBIPHBP is the atropoisomeric cliphosphine 2,2'- bis( diphenylphosphino) -6,6'-dimethoxy-1,l '-biphenyl, has been synthesized. In the presence of SnCl, this species is an efficient catalyst for the asymmetric hydroformylation of styrene.