Thermal dehydrogenation of 1,3-cyclohexadiene, cyclohexene, cyclohexane and ethylbenzene with cis-[PtCl2SnCl3)2]2− complex
✍ Scribed by Tetsu Yamakawa; Toshio Fujita; Sumio Shinoda
- Publisher
- Elsevier Science
- Year
- 1989
- Weight
- 250 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0304-5102
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## Abstract The dehydrogenation of 1,4‐cyclohexadiene (**1**) __cis__‐3,6‐dimethyl‐1,4‐cyclohexadiene (**2**) and __trans__‐3,6‐dimethyl‐1,4‐cyclohexadiene (**3**) with triphenylmethylfluoroborate in acetonitrile or 2,3‐dichloro‐5,6‐dicyanobenzoquinone (DDQ) proceeds in the same reactivity sequence
## Abstract It is shown that ligand **1**, designed to span __trans__‐positions, under appropriate conditions also gives __cis__‐mononuclear complexes of platinum (II). The structure of __cis__‐[PtCl~2~ **(1)**] **(2)** has been determined by single‐crystal X‐ray diffraction. The major distortion f