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Homogeneous catalysis. Titanium complex [Ti(Cp)2(CF3SO3)2] and zirconium complex [Zr(Cp)2(CF3SO3)2THF], efficient catalysts for the Diels-Alder reaction

✍ Scribed by Hollis, T. Keith; Robinson, N. P.; Bosnich, B.

Book ID
126054048
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
468 KB
Volume
11
Category
Article
ISSN
0276-7333

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Homogeneous catalysis. Use of the [TiCp2
Homogeneous catalysis. Use of the [TiCp2(CF3SO3)2] catalyst for the sakurai reaction of allylic silanes with orthoesters, acetals, ketals and carbonyl compounds.
✍ T.Keith Hollis; N.P. Robinson; John Whelan; B. Bosnich 📂 Article 📅 1993 🏛 Elsevier Science 🌐 French ⚖ 297 KB

## The effectiveness of the [TiCp2(CF$O3)2] catalyst for the Sakurai reaction has been exploredfor a variety of allylic silanes reacting with orthoesters, ace&, ketals, aldehydes and ketones. The Sakurai reaction (eqs 1.2) is promoted by a variety of Lewis acid@ including TiQ, Alc13, BF3, MesSi R'