Preparation, Spectroscopic Properties, a
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W. Petz; F. Weller; A. Barthel; C. Mealli; J. Reinhold
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Article
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2001
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John Wiley and Sons
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German
⚖ 253 KB
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The reaction of Na 2 [Fe(CO) 4 ] with Br 2 CF 2 in npentane generates a mixture of the compounds (CO) 3 Fe(l-CO) 3±n (l-CF 2 ) n Fe(CO) 3 (2, n = 2; 3, n = 1) in low yields with 3 as the main product. 3 is obtained free from 2 by reacting Br 2 CF 2 with Na 2 [Fe 2 (CO) 8 ]. The non-isolable monomeri