A novel kinetic and mechanistic study of
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Ch. Sanjeeva Reddy; E. V. Sundaram
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Article
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1983
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John Wiley and Sons
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English
β 511 KB
A detailed kinetic study of the Mn(1I)-catalyzed and -uncatalyzed oxidation of pinacol by bromate has been carried out in aqueous acetic acid media containing Hg(I1) ions. The uncatalyzed reaction exhibits 1.5 order that is, 0.5 order in [pinacol] and 1.0 in [bromate]. A decrease in k 1 by increasin