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Homogeneous catalysis of oxovanadium(IV) in the oxidation of substituted 4-oxo acids by bromate in acid medium: A mechanistic study

✍ Scribed by Cherkupally Sanjeeva Reddy; Padma Sunitha Manjari


Book ID
103835242
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
507 KB
Volume
328
Category
Article
ISSN
1381-1169

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A novel kinetic and mechanistic study of
✍ Ch. Sanjeeva Reddy; E. V. Sundaram πŸ“‚ Article πŸ“… 1983 πŸ› John Wiley and Sons 🌐 English βš– 511 KB

A detailed kinetic study of the Mn(1I)-catalyzed and -uncatalyzed oxidation of pinacol by bromate has been carried out in aqueous acetic acid media containing Hg(I1) ions. The uncatalyzed reaction exhibits 1.5 order that is, 0.5 order in [pinacol] and 1.0 in [bromate]. A decrease in k 1 by increasin