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Homochiral ketals in organic synthesis. Enantioselective synthesis and absolute configuration of (−)-modhephene

✍ Scribed by Eugene A. Mash; Shivanand K. Math; Christopher J. Flann

Book ID
118549809
Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
426 KB
Volume
45
Category
Article
ISSN
0040-4020

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📜 SIMILAR VOLUMES

Homochiral ketals in organic synthesis.
Homochiral ketals in organic synthesis. Enantioselective synthesis of [m.n.1] Propellanones
✍ Eugene A. Mash; Keith A. Nelson 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 241 KB

Optically active [m.n.l]propellanones have been prepared by diastereoselective cyclopropanation of homochiral ene ketals derived from 1,4-di-O-benzyl-L-threltol and readily available bicyclic enones. Propellanones are a synthetically useful subset of the structurally and theoretically interesting pr