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Synthesis, Absolute Configuration and Specific Rotation of (+)- and (−)-Modhephene

✍ Scribed by Prof. Dr. Lutz Fitjer; Dipl.-Chem. Honorato Monzó Oltra; Dr. Mathias Noltemeyer


Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
371 KB
Volume
30
Category
Article
ISSN
0044-8249

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✍ Prof. Dr. Dieter Seebach; Dipl.-Chem. Bernhard Seuring; Dr. Hans-Otto Kalinowski 📂 Article 📅 1977 🏛 John Wiley and Sons 🌐 English ⚖ 259 KB

vacuum distillation with exclusion of moisture affords 41.5 g (72 %) of ( 2), b. p. 55 "C/0.3 torr. ## 1 -Methyl-2-bis(trimethylsilyl)amino-2-trimethylsilylimino-3trimethylsilyl-4-tris(dimethylamino)-l,3,2,4A'-diazadiphosphetidine ( 3 ) : Compound (2) (1.92 g, 10 mmol) is added dropwise to a stirr