Angularly trijluoromelhylated crs-bicyclrc compounds were effectively produced by rntramolecular radical ondMchae1 addltron reactions As a ryprcai target molecule, 19,19.19-rrrfluorosreroid was prepared umg (~1 angularly tnfluoromethylated brcychc compound
Highly Trifluoromethylated Platinum Compounds
✍ Scribed by Dipl.-Chem. Sonia Martínez-Salvador; Prof. Dr. Juan Forniés; Dr. Antonio Martín; Dr. Babil Menjón
- Book ID
- 101838471
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 395 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0947-6539
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The reaction of enolate prepared from ethyl 3-methyl-4,4,4-trifluorobutyrate with Mo05-Py-HMPA complex provides ethyl (2S\*,3S\*)-2-hydroxy-3methyl-4,4,4\_trifluorobutyrate predominantly. In contrast, NaBH4 reduction of the corresponding 2-oxobutyrate affords (2R\* ,3S\*)-hydroxyester preferentially
IReceived in Japan 4 August 1969; received in UK for publication 4 September 1969) V./e wish to rewort on. a new method to in.troduce Cl?3 group into the desired Wosition of the aromatic rinq.
method and its modi®cations 7614 2.2. Aluminum-induced synthesis 7614 2