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Highly stereoselective SE' additions of .alpha.-alkoxy allylstannanes to chiral aldehydes. Synthesis of a C-1-C-9 subunit of tylonolide

✍ Scribed by Marshall, James A.; Yashunsky, Dmitry V.


Book ID
119956700
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
316 KB
Volume
56
Category
Article
ISSN
0022-3263

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Allyltitanates in Stereospecific Additions to Chiral Ξ΄-Lactol: Efficient Enantioselective Route to a Potential Precursor of the C 1 -C 9 Portion of Tylonolide. -The allyltitanate generated from the carbamate (I) is found to react with the aldehyde (II) to afford the anti adduct (III) with high dias