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Allyltitanates in Stereospecific Additions to Chiral δ-Lactol: Efficient Enantioselective Route to a Potential Precursor of the C1−C9 Portion of Tylonolide

✍ Scribed by Berque, Isabelle; Le Ménez, Patrick; Razon, Patrick; Mahuteau, Jacqueline; Férézou, Jean-Pierre; Pancrazi, Ange; Ardisson, Janick; Brion, Jean-Daniel

Book ID
126935833
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
126 KB
Volume
64
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Allyltitanates in S
ChemInform Abstract: Allyltitanates in Stereospecific Additions to Chiral δ-Lactol: Efficient Enantioselective Route to a Potential Precursor of the C1—C9 Portion of Tylonolide.
✍ Isabelle Berque; Patrick Le Menez; Patrick Razon; Jacqueline Mahuteau; Jean-Pier 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 38 KB 👁 1 views

Allyltitanates in Stereospecific Additions to Chiral δ-Lactol: Efficient Enantioselective Route to a Potential Precursor of the C 1 -C 9 Portion of Tylonolide. -The allyltitanate generated from the carbamate (I) is found to react with the aldehyde (II) to afford the anti adduct (III) with high dias