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Highly Stereoselective Conjugate Addition of ( R )- or ( S )-4-Phenyl-2-oxazolidinone to Nitroalkenes

✍ Scribed by Lucet, Denis; Toupet, Loïc; Le Gall, Thierry; Mioskowski, Charles


Book ID
127243803
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
117 KB
Volume
62
Category
Article
ISSN
0022-3263

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Enantioselective Synthesis of α-Amino Ac
✍ Denis Lucet; Stéphane Sabelle; Olivier Kostelitz; Thierry Le Gall; Charles Miosk 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 376 KB 👁 1 views

The addition of the potassium salt of (R)-or (S)-4-phenyl-products were converted into α-amino acids and monosubstituted 1,2-diamines of high enantiomeric purity. 2-oxazolidinone to monosubstituted nitroalkenes proceeded with very good diastereoselectivity. Several of the addition derivatives are in