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ChemInform Abstract: Enantioselective Synthesis of α-Amino Acids and Monosubstituted 1,2-Diamines by Conjugate Addition of 4-Phenyl-2-oxazolidinone to Nitroalkenes.

✍ Scribed by Denis Lucet; Stephane Sabelle; Olivier Kostelitz; Thierry Le Gall; Charles Mioskowski

Publisher: John Wiley and Sons
Year: 2010
Weight: 39 KB
Volume: 31
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200003192

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The addition of the potassium salt of (R)-or (S)-4-phenyl-products were converted into α-amino acids and monosubstituted 1,2-diamines of high enantiomeric purity. 2-oxazolidinone to monosubstituted nitroalkenes proceeded with very good diastereoselectivity. Several of the addition derivatives are in

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